Just thinking in terms of compared to microplastics and toxins in recycled plastic.
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Define “green”. In terms of CO2 it would obviously be horrible and incredibly stupid.
It’s done in many modern parts of the world in proper incinerators, to produce electricity. The emissions are closely managed.
Still not a great idea to burn recyclable resources. The stuff that would otherwise end up in a landfill, sure, but most plastics can be used again in some way.